BLANC - Blanc

Wavelength-selective Two-photon Phototriggers: novel monomers to the control of polymerisation and depolymerisation reactions with temporal and 3D spatial resolution – SelectTPE

Submission summary

Multifunctional caged molecules with functional levels that can be selectively activated upon exposure to light of different wavelengths will be developed. In order to achieve 3D resolution of the uncaging process, especial attention will be paid to chromophores with photosensitivity to and two-photon excitation. Reactive monomers and crosslinkers with different molecular architectures and functional states will be caged and their reactivity will be inhibited. Upon mixture with appropriate polymer precursors and irradiation, polymerisation and depolymerisation processes will be independently initiated depending on the selected irradiation wavelength. The final polymerisation/depolymerisation degrees will be controlled by the exposure dose. The application of this principle to the generation of new materials with phototunable properties will be tested in two different cases: novel resist materials for 3D photopatterning and smart hydrogels with tunable mechanical properties and swelling degree.

Project coordination

The author of this summary is the project coordinator, who is responsible for the content of this summary. The ANR declines any responsibility as for its contents.

Partner

Help of the ANR 0 euros
Beginning and duration of the scientific project: - 0 Months

Useful links

Explorez notre base de projets financés

 

 

ANR makes available its datasets on funded projects, click here to find more.

Sign up for the latest news:
Subscribe to our newsletter