CE07 - Chimie moléculaire

From Molecular Complexes to Synergic Multi-Switchable Fluorescent Solids – Mol-CoSM

Submission summary

The Mol-CoSM project, gathering three complementary french groups (Brest (1), Versailles (2) and Nancy (3)), deals with the design of new multifunctional complexes combining, in a synergetic way, molecular switching and fluorescence. Thus, in addition to the extensive synthetic work to the design new series of multifunctional systems, this project has three orientations: (i) the control of the fluorescence yield according to the nature of the fluorophore; (ii) the control of the switching parameters, such as the transition temperature and the cooperativity; (iii) the understanding of the electro-vibrational interactions between the fluorescent motif and the SCO center, so as to enhance the bi-functionality, to produce thermal bistability, both on the magnetic and fluorescent properties. The final objective is to propose new systems with enhanced multi-functionalities for potential applications such as new generations of magneto-optical switches and molecular multi-sensors.

Project coordination

Smail Triki (CHIMIE, ELECTROCHIMIE MOLECULAIRES ET CHIMIE ANALYTIQUE)

The author of this summary is the project coordinator, who is responsible for the content of this summary. The ANR declines any responsibility as for its contents.

Partner

CRM2 Cristallographie, résonance magnétique et modélisations
CEMCA CHIMIE, ELECTROCHIMIE MOLECULAIRES ET CHIMIE ANALYTIQUE
UVSQ - GEMaC Groupe d'études de la matière condensée

Help of the ANR 418,770 euros
Beginning and duration of the scientific project: January 2021 - 42 Months

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