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New catalysts for SAFe HYdrogen Release and use – SAFHYR
The two couples perhydrodibenzyltoluene/dibenzyltoluene and acetone/isopropanol involved in transfer hydrogenation operate in a closed circuit, with only hydrogen being able to enter and leave the circuit. This process, which is athermal and safe (no molecular hydrogen is released), could be a signi
Operando investigation of chemo-mechanical degradation in sulfide-based solid electrolyte – OpInSolid
All solid-state batteries based on thiosulfate solid electrolyte hold the promise of safer and more energetic batteries, especially once coupled to Li metal anode and high voltage cathodes. Unfortunately, it was demonstrated in the literature that their electrochemical stability window is far from o
Multiphysic Atomization with Diffused Interfaces for Real Air-blasted engiNes – MADIRAN
This project aims at studying air-assisted atomization and spray formation for aircraft engines in a complex multi-physic environment, with the use of advanced numerical methods. Large Eddy Simulations of reactive, two-phase and multi-components flows will allow to put light on atomization processes
High performance nanofluidic thermoelectricity using smooth polarized surfaces – smoothE
Waste heat energy discharged into the atmosphere is one of the largest sources of clean, fuel-free and inexpensive energies available. The most commonly used technologies to convert waste heat to electric energy are solid-state thermoelectric generators and liquid-based thermoelectrochemical cells.
Protection of O2 Sensitive Catalysts Under Reductive Conditions – PROSECCO
The implementation of energy conversion schemes involving dihydrogen and CO2 requires solutions that prevent the inactivation by oxygen of biological or synthetic catalysts that are based on cheap and abundant transition metals. The partners of the project have recently developed a strategy for usin
Photocatalysts based on Earth-abundant metals: towards a sustainable production of solar hydrogen – SunHy
In an attempt to fight against climate change and global warming, our global carbon footprint must be reduced to a minimum. This incredible challenging objective implies the use of sustainable sources of energy and raw materials, having become an intense focus of research in recent years. In this co
Spintronic harvesting of ambient thermal fluctuations – SpinElec
To maintain energy security in the face of a changing global climate, renewable energy sources are tasked with replacing fossil fuel-based sources. All energy harvesting strategies studied thus far exhibit tradeoffs. Natural energy sources can reach power densities P=100mW/cm2 (solar irradiation on
Microfluidics for controlling multiphase and species transport towards clean energy systems in the subsurface – GeoMIME
Multiphase flow in porous media is important in several environmental and industrial subsurface applications such as the sequestration and storage of CO2 in geological formations or soil remediation. Predictive capabilities of multiphase systems, however, must be improved. GéoMIME aims at examining
Machine learning for high temperature solar receivers – SOLAIRE
The SOLAIRE project concerns the application field of high-efficiency concentrated solar power (CSP) plants using pressurized air Solar Receivers (SR) at very high temperature around 1000 ° C (the temperature of the heat transfer fluids of current commercial CSP is below 565 ° C). To achieve these t
New strategy for bio-clogging remediation in porous media dedicated to geothermal energy – BIOCIDES
By 2028, the share of geothermal energy in the energy mix will double. To achieve this ambitious objective, the major problem of geothermal fluids circulation in aquifers has to be overcome in order to gain in plant efficiency. The microorganisms, evolving in these porous media, form biofilms that g
Search for new THERMOelectric and magnetic chalcogenides with DFT as a guiding tool – ThermoDFT
The search for thermoelectric materials is an active topic, and promising new families such as chalcogenides have emerged in recent years with the figure of merit ZT reaching 1 or above. One of the possible tuning parameters of ZT in chalcogenides containing transition-metal cations is magnetism whi
Analysis and characterization of pneumatic conveying of non-conventional solids – PHOBARS
The PHOBARS project (Pneumatic Handling Of Bio And Recycled Solids) aims at studying the pneumatic transport of non-conventional powders resulting from plastic wastes or second-generation biomasses. The scientific objective of the project is to understand the mechanisms and phenomena involved in the
Plasmonic molecular rectennas to produce electricity from light – PlasMORE-LIGHT
In line with the 2.1 scientific axis of the ANR call for project, the PlasMORE-LIGHT project proposes to study a breakthrough concept of rectennas aiming at converting light into electricity from visible to infrared. We explore a new paradigm, coming from the microwave community, in which the wave p
Large Size Diamond MOSFET – LSD-MOSFET
The ambition of the LSD-MOSFET project is to fabricate large size diamond metal oxide semiconductor field effect transistor on large size substrates operating at high voltage/high temperature. Project partners have recently developed new concepts based on the specific physical properties of ultra
Exploration of the microscopic mechanisms for colossal permittivity in Andersson-Wadsley titanium oxides – MIMETIX
Recent experimental work from the partners of this consortium has suggested the possibility to simultaneously observe colossal dielectric constant and superionic conduction in a family of titanium oxide materials. The proposed project aims at understanding the microscopical mechanisms at play in the
Boosting efficiency and selectivity in ORR and CO2RR by coupling metallic nanomaterials and molecular cavities – MARCEL
MARCEL 2.0 proposes an original concept where metallic nanocatalysts (Au, Ag, Cu nanoparticles) are functionalized with molecular hosting cavities bearing metallic complexes in order to direct the reactivity in ORR and CO2RR electrocatalysis. Both of these processes are complex and require efficient
A new concept of Proton Battery – H-BAT
In the current context of global warming, there is an urgent need to mobilize French research resources to reduce greenhouse gas emissions by accelerating the energy transition to renewable energies on the one hand and developing energy storage capacities on the other hand,. For new, efficient, sust
Influence of CONVection in suspensions of mIcroeNcapsulated phase Change materials in urban civil Engineering applicationS – Convinces
Key words: Phase Change Materials (PCM), Suspensions of micro-encapsulated Phase Change Materials (mPCM), Heat transfer, Convection, Physical characterization of mPCM and of the systems, Fluid mechanics, Energetics, urban environment, process optimization. Methodologies: Multi-scale and Multiphy
Photoactive hybrid porous solids for overall water splitting – MOFtoH2
Solar energy assisted overall water splitting (OWS) has emerged as a low-cost green technology to produce sustainable H2. Current photocatalysts suffer from a lack of viable solar-to-hydrogen (STH) energy conversion efficiency, stability under operation, easy synthesis routes, or inactivity under vi
Hydrothermal Molten Salts for High Mn(V) oxidation State Materials – HSM2
The (HSM)2 project proposes to develop a new synthesis process for the preparation of uncommon high oxidation state compounds, difficult to synthesize, for energy materials. The ambition of the (HSM)2 project is to extend the compositional range of the selected oxides and bring them at the forefront
Acid-Base Functionalization of Electrocatalysts Surfaces for Solid Oxide Cells – BATELCAT
The efficiency of electrode materials in solid oxide cells can be dramatically impacted by surface acidity. BATELCAT aims at using a simple infiltration protocol to modify the acidity of the surface of a wide range of mixed conducting metal oxides and systematically study their catalytic activity to
Dynamic behavior analysis of active species by modulation excitation spectroscopies: Application in heterogeneous catalysis – MESCAT
Heterogeneous catalytic steps are a synergetic interactions of reactives pecies with continuously evolving surface actives sites to promote the desirable reaction from complex manifolds of pathways. To achieve such a high level of selectivity, heterogeneous catalysts have to be tailored in a very pr
Materials and structures allowing very-low-bandgap thermophotovoltaic energy conversion – LOW-GAP-TPV
The objective of the project is to propose, fabricate and evaluate new materials and structures allowing very-low-bandgap (from 0.36 down to 0.17 eV) thermophotovoltaic (TPV) conversion of thermal energy from medium-grade heat sources ( < 1000 °C). As main requirements, the infrared photovoltaic cel
Cooling devices based on non-equilibrium transport in semiconductor heterostructures – GELATO
GELATO aims at designing disruptive highly efficient thermionic cooling nano-devices. It is motivated by the urgent technological need to control joule heating in nanoelectronics in a context of energy shortage. So far, most of the studies on solid-state cooling are based on the classical thermoelec
3D Atomic Scale Correlative microscopy and Electronic Simulation of light Emitters – ASCESE-3D
Current energy challenges lie not only in energy conversion and storage, but also in reducing energy consumption. The use of light emitting diodes (LEDs) is widely spread today in lighting, signaling, displays, computing, telecommunication or disinfection. The power conversion efficiency of blue LED
A little bit of SALT, but not too much: Prevent hyPERtension in all-solid-state batteries – SALT-PPER
All solid-state batteries (ASSB) have the potential to outclass state-of-the-art Li-ion batteries, provided several key challenges are solved. Among them, the interface between the positive electrode material and the solid electrolyte is a source of large interfacial resistance, progressively leadin
Understanding charge separation in photosynthetic reaction centers II by a novel spectroscopy of gas phase chlorophyll constructions – ELECTROPHYLLE
The Electrophylle project seeks to characterize a fundamental process involved in the initial transformation of light energy in the reaction center of Photosystem II that initiates photosynthesis in plants and algae. Electrophylle will create a synergy around a new gas phase experimental method appl
Non-linear electromechanical effects in ZnO nanowires for enhanced energy conversion – LATINO
Piezoelectric (Piezo) semiconductor (SC) nanowires (NWs) have been researched as the building blocks for various energy transducing applications including mechanical energy harvesting, sensors and piezotronic devices, exploiting both the SC and Piezo properties to control the electric transport thro
Storage and Conversion of SOLar energy via PHOTOchemical and CATalytic reactions – SOLPHOTOCAT
The project SOLPHOTOCAT is willing to investigate the development of new chemical devices for the storage and the release on demand of solar energy. The targeted system is a chemical system capable of (i) conversion of solar energy into a storable chemical energy via a photochemical transformation o
POM@MOF composites for photocatalytic CO2 reduction – PMCOCAT
One of the major challenges in the field of photocatalysis is the development of noble-metal free, efficient, selective and recyclable catalysts. By combining our complementary expertise, our consortium proposes to develop, characterize and study the properties of metal-organic framework (MOF) photo
Modeling photonastic materials: from the molecular to the mesoscopic scale. – PHOTONASTIC
Photonastic materials convert light energy into mechanical energy and are the subject of pre-determined and repeatable deformations in response to light stimulus. This project aims at identifying the key parameters at the molecular and supramolecular scales involved in the mechanical response of a p
Accelerating the demonstration of Gallium Oxide’s outstanding potential for Energy application – GOPOWER
GOPOWER project concerns “Basic Science for Energy” axis. Ga2O3 is an emerging ultra-wide bandgap semiconductor material for future high-power devices (beyond 6.5 kV) devoted to energy applications such as electric transportation and smart grids. All Ga2O3 power devices demonstrated so far have been
Reactive fluids to intensify thermal energy conversion – REACHER
Thermal engines, refrigeration systems and heat pumps rely on thermodynamic cycles, in which an inert working fluid converts input thermal and mechanical energies into another useful energy form (work or heat) by cyclically transforming its thermal energy content. Although the selection of the worki
Multi-scale matching for flows with a grid – MultiMatchGrid
A novel first principle approach will be proposed for dealing with multi-scale laminar, transitional and turbulent flows across weakly porous grids. Taking advantage of the separation of scales due to the small size of the grid pores, MultiMatchGrid will match the large far-grid to the small near-gr
Confinement of Molecular Electrocatalysts in Porous Metal Organic Host Cages for selective CO2 electroreduction – CONFI-Cat
CONFI-Cat develops the design and the elaboration of innovative hybrid catalysts for selective and stable CO2 electroreduction. The reactivity and stability of the molecular catalysts are controlled by encapsulation. Molecular cages are used as matrices to structure, modify and control the local env
Graphene Remote Epitaxy for Solar Cells – A-PROPOS
Record efficiency solar cells are made of III-V materials, but their usage is limited to niche applications due to their high cost. More than 80% of this one is made up by costly substrates, so that a method to recycle them for several consecutive growths would constitute a breakthrough for high-eff
Heat transfer analysis at the transition from convective to nucleate boiling regimes for heat transfer enhancement in the energy technologies of the future – TraThI
In the energy technologies of the future, the thermal power densities to be transferred will be greater than 1000 W.cm-2. Current techniques do not allow the extraction of such high power densities. To meet these challenges, new concepts must be implemented. In this context, thanks to a multi-scale
Platform for multisCale simulation of hot carriers: electrons and phonons for energy harvesting – PlaCho
The project Placho (Platform for multisCale simulation of hot carriers: electrons and phonons for energy harvesting) aims to develop an original multi scale (DFT+Monte Carlo+NEGF) numerical platform from atoms to device specifically dedicated to energy conversion. This versatile tool based on first
Ionic liquids for Nano-structuration and Surface functionalization of Electrode Materials – Nano-INSPIRE
Nanosizing electrode materials permit greatly improved ionic and electronic conductivities. Nevertheless, some challenges associated to the reactivity of nanomaterials remain due to their high specific surface area, which leads to parasitic and often irreversible reactions and strong interaction wit
Reduction of N2 to NH3 with Mo complexes. From fundamental PCET reactivity to efficient electrocatalysis – REDNEC
The Haber-Bosch process leads to the synthesis of ca 200 million tons of ammonia per year, mostly used as fertilizer. This process combines N2 and H2 using heterogeneous catalysts under drastic conditions, and it consumes between 1 and 2% of the annual worldwide primary energy produced, leading to m
Water-based magnesium innovative energy storage – MAGWAT
Water-based solutions play a key role in the realm of biology, chemistry, and more particularly, in energy-related fields such as photo and electro-catalysis and batteries. While aqueous batteries were believed to be constrained by the thermodynamic electrochemical stability window of water (1.23 V
Flexoelectricity in soft conjugated polymer films – Flex-SCO
The project deals with experimental and theroretical study of ambient mechanical energy harvesting with flexoelectric-like polymer films. The considered transduction mechanism is the flexoelectric effect which corresponds to an electrical polarization induced by a strain gradient. This effect is exp
Bio-inspired synthetic matrices for efficient electrocatalytic CO2 reduction – MatriCORe
Despite important progresses made over the past few years towards the development of new molecular structures the electrocatalytic reduction of CO2, such catalysts still mostly remains far from potential industrial applications, mainly due to a lack of control of the reactivity and stability of the
Hybrid photovoltaic-thermoelectric systems for solar energy harvesting – HYDRES
Despite recent conceptual and technological advances, the conversion efficiency of single-junction solar cells is still limited to 33%. In particular, depending on the photovoltaic material, up to 50% of the solar energy striking the cell is lost and dissipated as heat. An emerging strategy for harv
Clay-based adsorbents for biogas upgrading – CLAYGAS
Nanoporous materials derived from clays feature textural properties and volumetric gas adsorption performances comparable to those of traditional industrial adsorbents for gas treatment process, such as bio-methane upgrading by CO2 capture. In this specific context, we have recently shown that smect