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Electronically active thin-films for new concepts of Nano-devices
The goal of this project is to make decisive progress in the integration of photo/piezo/electro-switchable molecules into nanodevices. To this end we will explore the potentialities of an innovative low-cost strategy based on the controlled electro-polymerization of robust switchable cubic complexes
Multimodal nanoprobes for high resolution and high penetration imaging
The combination of nano-bio technology with innovative therapeutic approaches have led to many successful proof-of-principle demonstrations in the last decades, which foster the hope for new diagnostic/therapeutic strategies for different types of diseases. However, the translation of this approach
Towards FLEXible and versatile Ferroelectricity in perovskite Oxides
Ferroelectric (FE) oxides are efficient functional ingredients for the development of tomorrow’s electronics, for instance in low-power memories and bio-inspired devices. Their ferro-, piezo- and flexo-electric properties are always coupled to strain imposed by epitaxial growth onto an oxide substra
Programmable self assembling functional Origami from designed protein
The objectives of the ProteOrigami project are to design, produce and characterize self-assembling supramolecular Protein Origami and to use this new platform to precisely organize optical nanomaterials in space. This experimental project gathers four partners with complementary expertise in protein
Lead-free piezoelectric nanowire-nanocellulose hybrids for flexible energy harvesters
A large number of small-scale electronic devices are increasingly integrated in our everyday lives. Future requirements for these devices are to be sustainable, maintenance-free, and self-powered (free of batteries). In this regard, nanowire (NW) based piezoelectric energy harvesters have emerged as
Temperature profile in nanomagnet based hyperthermia devices
Magnetic hyperthermia consists in converting electromagnetic power into heat by applying an external AC magnetic field to an assembly of magnetic nanoparticles. A very localized temperature rise is then observed, which can be useful in medicine or chemistry, especially catalysis. However, although v
Hybrid photostrictive-magnetic nanocomposites
Within the framework of CE 09 - "Nanomaterials and nanotechnologies for the products of the future", the HYPNOSE project proposes to follow a new path in the manipulation of the magnetization by combining the development of hybrid systems and the optical control of magnetization. Our approach is bas
Intelligent Real-time MAnipulation of metal nanostructure growth
IRMA seeks to develop efficient and non-invasive strategies for manipulating the morphology and the opto-electronic properties of vapor-deposited Ag nanostructures grown by magnetron sputtering at room temperature (i.e., 3D islands and ultrathin continuous layers). This will be achieved via selectiv
POlymer Membranes for personal thermal COmfort MAnagement
In France, the building sector is the most energy consuming sector (43% of total energy), with 65% of this part directly linked to HVAC systems. The POCOMA project aims at reducing this energy consumption by shifting the problem of thermal comfort from the building scale to the level of the person t
Electrically-Excited Chiral Plasmonic NanoCavities
Chiral structures, whose initial and mirror structural images cannot be superimposed, interact differently with left-handed and right-handed circularly polarized light. Thus a structure of a certain “handedness” preferentially scatters or absorbs circularly polarized light of the same handedness, le
Phosphate capture enhancement in peritoneal dialysis process using designed recyclable iron oxide nanostructures
In patients suffering of chronic kidney disease (CKD), phosphates accumulation in blood is very dangerous and dialysis is the only way to remove them from blood, for those waiting for transplantation. Phosphate imbalance leads to a high cardiovascular mortality and to bone disorder in dialysis patie
Photochemistry and phOtophysics of Plasmons towards fully COntRolled Nanolocalized polymerization
Optically excited plasmonic nanoparticles (NPs) can advantageously be used to activate chemical transformations directly and locally on their surfaces, opening interesting prospects in many areas. Despite numerous demonstrations, the exact mechanisms and main parameters driving the control of plasmo
Surface spin-state manipulation in semiconducting nanoparticles
Within the frame of the nanostructures surface functionalization, this project aims to generate, to manipulate, and to detect magnetic states localized at the surface of semiconducting and polar zinc oxide nanoparticles (NPs), by electron paramagnetic resonance (EPR). The monitoring of such surface
2D nanolaminate - nanofluidic ionic diodes hybrid membranes for desalination and water purification (2D-MEMBA)
Nanomaterials hold promise for the development of innovative membranes towards the purification of water and desalination. Two-dimensional materials (2D) when stacked in 2D nanolaminates have been investigated for molecular sieving via size-limited diffusion in the 2D capillaries while nanofluidic i
Tailoring topological states in multiferroics
In the TATOO project, we will first initiate ferroelectric landscapes harbouring polarisation windings in nanostructured multiferroic BiFeO3 thin films. We will promote various polarisation configurations (centre domains or vortices), and observe the corresponding spin winding textures inherently in
design & Control of spIn, orbiTal and chaRge Orders in vaNadates
The ever-increasing development of information technologies raises not only the question of the energy supply of the electronic devices but also of handling a massive number of operations and managing multiple collections of data. Besides the needs for innovative renewable energy sources and miniatu
Active spin-crossover/graphene interfaces for bistable electronic devices
The 2DSwitch project address the synthesis, characterization and basic understanding of a new family of active hybrid interfaces combining a 2D graphene(Gr) sensing layer in contact with an ultrathin film of switchable spin-crossover (SCO) sublimated molecules. Our main goal is to demonstrate bista
Luminescence Nanothermometry for the control and understanding of magneto-induced process. Application to biological hyperthermia and heterogeneous catalysis in solution
The NANOTHERMOMETRY project aims to monitor the local temperature on the contact of nanoparticles heated by activation under an alternating magnetic field using luminescent particles. The two particles will be co-located in order to adjust the distance between the heat source and the measurement poi
Mixed Dimensional Heterostructures under 2D Ferroelectric control
MixDFerro project targets the elaboration and fundamental study of the structural, electronic, optical properties of novel two dimensional (2D) ferroelectric materials and their van der Waals heterostructures (vdW-h) with 2D and 0D semiconductors. We will first address a set of basic questions such
Up-conversion ferroelectric nanocrystals for optical sensing of electric potential in biological systems
Most living cells exhibit a difference in electrical potential across their plasma membrane resulting from differences in ion concentration maintained by ion channels and pumps. The membrane of a neuron can be suddenly (˜1 ms) depolarised (its intracellular potential rising from -70 mV to +30 mV) by
In-plane core-shell nanowires with strong spin-orbit coupling for scalable mesoscopic devices
In semiconductors with strong spin-orbit (SO) coupling and broken inversion symmetry, electron momentum is locked to its spin via the Rashba effect. This property had important consequences in the design of spintronic devices such as the electrically gated spinFET, in the charge-spin inter-conversio
Graphene Nanomeshes
The aim of the project GANESH is to design and fabricate via the bottom-up approach 2-dimensional graphene sheets containing a well-defined network of holes (nanomeshes) and to evaluate their optical and electronic properties through a combination of advanced experimental and theoretical studies.
Control of the optical Absorption Properties of nanovectors for PHOTOACoustic imaging
Drug nanovectors (NVs) are expected to profoundly change therapeutic treatments in highly prevalent diseases such as rheumatoid arthritis. However, NV accumulation can be heterogeneous and a patient selection, based on imaging of NV fine localization, could improve treatment efficacy. The CAP-PHOTOA
Carbon nanotubes for integrated nonlinear optics
The baseline for the CARBONIC research project is to study, control and exploit the nonlinear optical properties of carbon nanotubes (CNTs)for the development of innovative linear and nonlinear functionalities in subwavelength integrated silicon nitride (SiN) nanostructures. The original idea is to
Morphology-controlled nanomaterials to understand and predict protein corona
Since the 1970’s, nanomaterials (NM) have had a powerful impact on biomedical applications such as imaging, diagnosis, drug delivery and targeting. This had led researchers to design a myriad of different NM classes without anticipating the complexity of their behaviors in vivo. Indeed, following ex
Block-cOpolymer Nano-manufacturing via Spatially controlled interfAce and wettIng manipulations
In microelectronics and nanoscience, geometrical scaling is still at the heart of the work and a wide range of technologies are used to further push the resolution. Directed Self Assembly (DSA) lithography is one of these and key demonstrations based on thin films of organic block copolymers (BCPs)
Nucleation, seed-mediated growth and Integration of Magnetic nanoRods
The NIMRod project gathers basic research on magnetic nanorods (NR) from their synthesis in liquid phase to the engineering of their assembly into permanent magnets (PM) of controlled size in the submillimetre range to meet the microelectronics demand for integrated devices. The project relies on re
Heterogeneous nanocrystals For Near-infrared BioImaging
The proposed project stems from the need to increase the depth of exploration in photonic imaging of biological tissues. As a solution to this problem, we propose to use infrared techniques for a wavelength located at the minimum of absorption of the biological medium. Nanocrystals with a precise co
Multiscale Monocrystalline Nanopatterns for Opto(nano)electronics
Material properties and nanoscale geometry are crucial pillars upon which the performance of optoelectronic devices stands. Monocrystalline materials are required to reach the highest possible performance, while the accurate design of the nanoscale geometry provides the opportunity to engineer light
Electron Excitations in Planar Interfaces
2D materials (graphene, hexagonal boron nitride, others) exhibit remarkable electronic properties which strongly depend on their chemical and physical environment. So, combining several 2D materials in the same heterostructure permits to modify and control their properties. In lateral heterostructur
Chiral Induction from Microns to Electrons for Radiative Anisotropy
The project will explore how organized assemblies of helical objects can give rise to a supramolecular response that can result in the induction of chirality from the helices to fundamental particles such as photons or electrons. This will represent an unprecedented leap in the understanding of how
Optical nanotweezer for single CELL stuDies : from mANipulation to mechaniCal propErties
CellDance is a fundamental project exploring a new kind of optical nanotweezers for single cell mechanical studies. Our objectives are twofold: • The first one is dedicated to a totally new concept of nanotweezer based on metasurfaces with controlled dispersion properties. We expect that it will all
Chemically addressing high curvatures at the nanoscale to optimize light-matter interactions
Light-matter interactions at room-temperature are fundamentally limited by electron-phonon interactions. While a single quantum emitter at cryogenic temperatures can interact with ~50% of incoming photons, this value is reduced by 7 orders of magnitude at room temperature. Plasmonic resonators have
Interaction of biological targets with solid dielectric layers consisting of silver nanoparticles embedded in silica matrices: Towards tailored antimicrobial surfaces
The emergence and selection of antibiotic-resistant bacteria is an ever increasing Public Health problem. Microbial adhesion and subsequent biofilm formation are at the origin of hospital-acquired infections, often leading to septic complications and lethal issues, and entailing large economical los
Alloyed Materials for PHOtonics: exploring dielectric REsponse in group IV nanowires
Achieving light emission from group IV elements has been representing a pot of gold in modern Si technology for decades, involving generations of scientists trying to make Si and SiGe alloys optically active. Over the last few years, the emergence of data-intensive technological areas has made the n
van der Waals heterostructures opto-magnetomechanics
The emergence of atomically-thin van der Waals materials offers great opportunities to develop next-generation devices for nano- electronics and photonics. The recent demonstration of an intrinsic magnetic order in atomically-thin van der Waals materials (MVM) opens a vast playground to understand a
Single NanoAlloy Particle Structure and Spectroscopy
Bimetallic nanoparticles (BNPs) are important for fundamental research and for applications as their physicochemical properties can be tuned by controlling their chemical composition, size and environment. But the in-depth understanding of the role of the various parameters, required for this tuning
PhysIcAl properties of hybrid semimetal/semicoNductor III-V/Si maTerials
The monolithic integration of III-V semiconductors having excellent structural and optical properties on the low cost and technology mature silicon substrate was long ago considered as an unattainable holy grail for many materials and devices scientists. The situation changed recently with the vario
Intracellular process activation by local warming: designing multifunctional nanoprobes with high intracellular mobility after internalization
The activation of cellular processes with magnetic nanoparticles (MNPs) is an emergent topic, but tools are still lacking to widen the potential applications. Indeed, if some intracellular targets could be of great interest, they are yet to be reachable due to the cellular internalization pathways o
Magnetic molecularly imprinted polymer nanoparticles for cell targeting and controlled drug release
Breast cancer is a heterogeneous disease that accounts for 30% of all cancers diagnosed in women and over half a million deaths per year. Breast cancer stem cells (BCSCs) make up a small subpopulation of cells within a tumor are responsible for tumor initiation, formation, and recurrence. BCSCs have
New ultrathin oxide films on metal substrates
Ternary oxides with perovskite structures ABO3 have two cationic species that can be selected among transition metals, lanthanides, simple metals, rare earths or even alkalis. So many possible associations result in a large class of materials exhibiting various properties, from superconductivity to
Photo-Induced On-Surface Synthesis to Elaborate Highly-Ordered Covalent Structures on Insulating Substrates
Light4Net is a collaborative project which enrolls two major French academic research laboratories (IM2NP and FEMTO-ST), each labelled “research centre of excellence” by the French government. The partners have already proven a fruitful and close collaboration in the past. Light4Net presents an enti
Graphene layer patterned by diamane/graphane areas towards in-plane sensor device
The GLADIATOR project aims to pattern monolayer or bilayer graphenes areas of sp3 carbon called graphane or diamane within a sp2 carbon film, in order to study their properties and use them in micro- and nano-scale applications. The very first demonstration of a successful synthesis of diamane was m
Controlled Reactivity of Sulfoxides on Insulating Surfaces
On-surface synthesis has emerged as a powerful way to produce new functional nanomaterials and extended molecular structures, which cannot be prepared by “conventional” in-solution synthetic chemistry. Starting from tailor-made molecular precursors, a variety of complex nanoarchitectures exhibiting
Borophene Chemical Synthesis
The recent synthesis of borophene, a one-atom thick 2D crystal of boron, has brought forward a major missing piece of the 2D construction game: a stable metallic 2D material. Thanks to its exotic properties, borophene could lead to numerous applications such as efficient, flexible and transparent el
Studying nucleation in nanoparticles synthesis using machine-learning assisted atomistic simulation
A key challenge in today’s nanotechnologies is the control of the structural properties during the nanoparticle synthesis. Reaching a targeted synthesis of nanoparticles requires a much better understanding of the involved complex mechanisms and in particular of crystal nucleation which corresponds