Push-pull tandems based on metal CLUSters and PolyOxoMetalates for solar production of H2 – CLUSPOM-H2
The project targets to design functional supramolecular systems based on mixed inorganic molecular building blocks combining “electron-poor” thio-polyoxometalates (thio-POMs) and “electron-rich” octahedral clusters (CLUSs) with complementary optical and electronic properties. The thio-POMs will serve as efficient redox catalysts, while CLUSs will act as robust photosensitizers. Hybrid thio-POM-CLUS assemblies will be employed as through space electron donor-acceptor tandem for visible light driven photocatalytic hydrogen evolution reaction (HER). The photo- and photoeclctro-catalytic process will be studied first in homogeneous systems to establish conditions and experimental parameters for optimum performances. In a second step, the molecular thio-POM-CLUS tandem will be integrated into compartmentalized photoelectrochemical cells. Advanced photophysical characterization and modeling will be employed to get insights into mechanism of photo-induced electron/energy transfer processes.
Monsieur Mohamed Haouas (Centre national de la recherche scientifique)
The author of this summary is the project coordinator, who is responsible for the content of this summary. The ANR declines any responsibility as for its contents.
ISMO Centre national de la recherche scientifique
ISCR INSTITUT DES SCIENCES CHIMIQUES DE RENNES
ILV Centre national de la recherche scientifique
Help of the ANR 588,323 euros
Beginning and duration of the scientific project: September 2022 - 48 Months