CE07 - Chimie moléculaire

Controlled Delivery of Isotopically Labelled Singlet Oxygen – DelivrO2

Submission summary

Among the various elements present in organic molecules, oxygen plays a key role in many functional groups, and its isotopic labelling often provides determinant mechanistic evidences in chemical reactions and biological studies. Whereas using singlet oxygen (1O2) is a convenient strategy to incorporate oxygen atoms in organic compounds in extremely mild conditions, the direct transfer of the existing conditions involving large excesses of O2 is too costly for practical applications in isotopic oxygen labelling. In this context, the DelivrO2 project proposes the development and the use of new endoperoxides that will allow the efficient and temporally / spatially controlled releases of stoichiometric amounts of isotopically labelled [*O]1O2 for both synthetic and biological applications.

Project coordination

Philippe Hermange (Université de Bordeaux)

The author of this summary is the project coordinator, who is responsible for the content of this summary. The ANR declines any responsibility as for its contents.

Partner

ISM Université de Bordeaux
CEISAM CHIMIE ET INTERDISCIPLINARITE : SYNTHESE, ANALYSE, MODELISATION
IBMM Centre national de la recherche scientifique

Help of the ANR 481,552 euros
Beginning and duration of the scientific project: December 2022 - 48 Months

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